Preservatives & Antimicrobials

Sodium Hydrogen Sulphite

Sodium Hydrogen Sulphite, also known as Sodium Bisulphite or Sodium Bisulfite, is a sulphite-based preservative and antioxidant used in selected food and beverage systems for microbial stability, oxidation control, anti-browning, color protection and sulfur dioxide contribution where permitted. It is reviewed by manufacturers that need a reactive sulphite source with controlled active content, suitable packaging, clear safety information and reliable regulatory documentation.

For industrial buyers, Sodium Hydrogen Sulphite should be evaluated as a reactive processing and preservation ingredient rather than a generic preservative. Performance depends on SO2 equivalent content, solution concentration, pH, food matrix, oxygen exposure, process timing, residual sulphite level, storage conditions, allergen-label requirements and destination-market rules.

Sodium Hydrogen Sulphite food additive food additive ingredient illustration

Product identity

ProductSodium Hydrogen Sulphite
Alternative spellingSodium Hydrogen Sulfite
Common namesSodium bisulphite, sodium bisulfite
CategoryPreservatives & Antimicrobials
FunctionPreservative / antioxidant / anti-browning agent / sulphite source
E / INS numberE222 / INS 222
CAS / identity7631-90-5
Chemical formulaNaHSO3
Ingredient familyInorganic sulphite / bisulphite salt
Typical formSolution grade, powder, granule or stabilized blend depending on supplier specification and active basis
Main technical roleSO2 source, oxidation control, microbial stability support, enzymatic browning reduction and color protection
Use statusConfirm permitted food categories, maximum sulphite levels, residual SO2 limits and label declaration by destination market

Application fit

Potential use areas may include controlled and legally permitted systems such as:

  • Fruit juices, concentrates, syrups and beverage bases
  • Wine, cider and fermentation-related beverage processing where permitted
  • Dried fruits, fruit preparations, jams, fillings and toppings
  • Potato products, peeled vegetables and anti-browning treatments
  • Shrimp, crustaceans and selected seafood treatments where permitted
  • Sauces, pickles, condiments and acidic food systems
  • Starch, sugar, gelatin and specialty processing applications
  • Industrial premixes or solutions requiring controlled sulphite functionality

Industrial function and preservation value

Sodium Hydrogen Sulphite is valued because it provides bisulphite and sulphite functionality in food systems. In water and acidic environments, it can contribute sulfur dioxide-related activity, which may support antimicrobial protection, oxidative stability and enzymatic browning control. These effects can help protect color, flavor, aroma and shelf-life performance in suitable food matrices.

Its commercial value is measured by finished-product performance and compliance, not simply by price per kilogram. A suitable food-grade supply should provide consistent active content, predictable SO2 equivalent contribution, controlled impurity limits, proper packaging, strong traceability and reliable technical documentation. For sensitive export products, regulatory and allergen-label documentation can be as important as product performance.

Important: Sodium Hydrogen Sulphite can release sulphur dioxide, especially in acidic or moist conditions. It requires appropriate ventilation, PPE, secure storage, allergen-label review and controlled dosing procedures. Final suitability must be validated through formulation trials, residual sulphite testing where required and destination-market regulatory review.

Technical specification points to compare

Composition and assay

  • Assay or active content on the supplier's declared basis
  • SO2 equivalent content or sulfur dioxide contribution basis
  • Solution concentration, density or dry matter where applicable
  • Sulphite, bisulphite and related sulphur-species specification where applicable
  • pH of solution and acidity/alkalinity values where specified
  • Food-grade compliance and intended-use declaration
  • Compliance with food additive, FCC, JECFA, EU or customer-specific standards where required

Impurity and safety controls

  • Heavy metals and elemental impurity limits
  • Lead, arsenic, cadmium and mercury statements where required
  • Iron content where color stability is critical
  • Chloride, sulfate, thiosulfate or insoluble matter where specified
  • Foreign matter, color, odor and appearance controls
  • Microbiological statement where relevant to the supplied grade
  • Allergen, GMO, irradiation and contamination statements where required

Physical properties

  • Liquid concentration, density, clarity and color for solution grades
  • Particle size, bulk density and flowability for dry or blended grades
  • Solubility and dissolution speed in the target process
  • Dusting tendency and operator exposure considerations
  • Moisture sensitivity, oxidation tendency and SO2 odor release
  • Color, odor and visual appearance of the supplied grade
  • Compatibility with dosing equipment, solution preparation and premix handling

Process compatibility

  • Suitability for solution dosing, dipping, spraying, inline addition or controlled premix use
  • Compatibility with product pH, acids, sugars, minerals, colors and flavors
  • Impact on residual sulphite, flavor, aroma, color and label declaration
  • Effectiveness in anti-browning, oxidation-control and microbial-stability systems
  • Interaction with packaging oxygen, headspace and storage temperature
  • Influence on allergen labeling, additive limits and customer specifications

Formulation and application guidance

Sodium Hydrogen Sulphite should be selected according to the target function: preservation, antioxidant protection, enzymatic browning control, color stabilization, oxygen scavenging or processing aid functionality. The effective sulphite species and residual sulphite profile depend strongly on pH, food composition, oxygen exposure, contact time, temperature and processing sequence.

Antioxidant and anti-browning performance

Sodium Hydrogen Sulphite can help slow oxidative quality loss and enzymatic browning in selected systems. In fruits, vegetables and seafood, it may reduce browning reactions by interacting with reactive intermediates and oxygen-sensitive components. In beverages and acidic foods, it can support flavor and color stability by helping control oxidative pathways.

Because sulphite chemistry is reactive, formulation trials should measure both technical performance and residual levels. A formulation may show excellent anti-browning but exceed permitted residual sulphite limits or create undesirable sensory notes. A practical approval program should balance preservation performance, sensory quality, residue compliance, allergen declaration and customer acceptance.

Performance drivers

  • Product pH and buffering capacity
  • Dissolved oxygen and headspace oxygen
  • Enzyme activity and raw material maturity
  • Temperature, contact time and mixing quality
  • Moisture level and water activity
  • Packaging barrier and storage conditions
  • Residual SO2 target and label threshold

Typical validation work

  • SO2 equivalent calculation and dosing trial
  • Residual sulphite or total SO2 testing where required
  • Color and browning-index measurement
  • Oxidation and flavor-stability testing
  • Microbiological shelf-life testing where relevant
  • Packaging and oxygen-exposure assessment
  • Label and regulatory confirmation before launch

Preservative-system design

Sodium Hydrogen Sulphite is usually part of a broader preservation and quality-control strategy. Its performance may be combined with low pH, heat treatment, water-activity control, hygienic processing, oxygen management, chilled storage, preservatives, antioxidants or packaging control. The right system depends on the food category, microbial target, spoilage risk, expected distribution conditions and destination-market limits.

In acidic systems, sulphite functionality can be strong, but this also increases the importance of ventilation, odor control, dosage accuracy and residual monitoring. In products with high oxygen exposure or weak packaging protection, sulphite may be consumed more quickly, reducing shelf-life benefit and changing residual levels over time. Finished-product validation should therefore include real process and storage conditions.

Sodium Hydrogen Sulphite compared with related sulphites

Sodium Hydrogen Sulphite belongs to a wider sulphite family. It should not be substituted one-for-one with sodium metabisulphite, potassium metabisulphite, sodium sulphite, potassium hydrogen sulphite or sulphur dioxide solutions without technical and regulatory review. Each ingredient differs in cation contribution, SO2 equivalent, pH behavior, solubility, handling profile and label implications.

Ingredient Typical consideration
Sodium Hydrogen Sulphite Bisulphite source used for preservative, antioxidant and anti-browning applications where sodium contribution and supplier form are suitable.
Sodium Metabisulphite Common solid sulphite source with different SO2 equivalent and handling profile; often used where metabisulphite form is preferred.
Potassium Metabisulphite Alternative metabisulphite source considered where potassium contribution is preferred, especially in certain beverage and wine systems.
Sodium Sulphite Different sulphite salt with different alkalinity, assay and process behavior; not directly equivalent in all applications.
Potassium Hydrogen Sulphite Alternative bisulphite source where potassium contribution is preferred; suitability depends on regulation and sensory target.
Sulphur Dioxide Solution Direct SO2 source with stronger handling, safety and dosing considerations; typically requires specialized controls.

Quality and food safety review

A robust Sodium Hydrogen Sulphite sourcing review should include more than basic identity and price. Buyers should confirm exact grade, intended-use suitability, active content, SO2 equivalent basis, pH, impurity profile, packaging integrity, shelf life, origin, traceability, supplier qualification and change-control capability. For audited beverage, fruit, vegetable, seafood, sauce and export supply chains, documentation quality is as important as product performance.

Before commercial approval, compare the supplier specification against the intended product category, process conditions, residual sulphite requirement, customer requirements and destination-market additive rules. If Sodium Hydrogen Sulphite will be used in an export product, regulatory and labeling review should be completed before production scale-up.

Regulatory and labeling considerations

Sodium Hydrogen Sulphite is associated with E222 / INS 222, but permission depends on destination market, food category, maximum permitted level, residual sulphite or SO2 limits, technical need, label declaration and allergen-label requirements. Many markets require sulphite declaration when residual levels exceed defined thresholds, and some customers may impose stricter internal limits than local law.

Label declaration may require the ingredient name, additive class, E number, INS number, sulphite allergen statement or market-specific wording. Residual sulphite testing, production records and dosing documentation may also be required by regulations, customer specifications or internal food-safety plans.

Global Food Additives can support supplier communication and document collection; however, final responsibility for regulatory approval, use level, finished-product labeling, allergen declaration, safety validation and market placement remains with the buyer, importer, brand owner or manufacturer.

Documents to request

Packaging, storage and logistics

Sodium Hydrogen Sulphite packaging should protect the product from contamination, oxidation, moisture imbalance, leakage, odor release and handling damage. Depending on supplier format, it may be supplied in sealed drums, jerry cans, IBCs, lined containers, bags or solution containers. Packaging should support clear identification, traceability, product stability and safe industrial handling.

Commercial purchasing notes

For industrial purchasing, quotation accuracy depends on the quality of the inquiry. The most useful request normally includes target grade, reference specification, required active content, SO2 equivalent requirement, concentration or form, packaging size, destination country, delivery term, required documents, expected shipment date and any special safety, transport or labeling requirements.

If the buyer already uses Sodium Hydrogen Sulphite, sharing an existing COA, label, TDS, SDS or internal specification helps compare alternatives more accurately. It is also useful to mention the final product type, current sulphite system, residual SO2 target, whether the product is domestic or export, and whether solution, powder, granule or premix format is preferred.

Best-fit inquiry details

  • Product name: Sodium Hydrogen Sulphite
  • Alternative name accepted: Sodium Bisulphite / Sodium Bisulfite
  • Required food grade and intended application
  • E222 / INS 222 declaration requirement
  • Assay, active content, SO2 equivalent, concentration and impurity expectations
  • Solution, powder, crystal, granule or premix preference
  • Quantity, annual forecast and repeat-order potential
  • Destination country and delivery term
  • Preferred packaging, safety label and language
  • Required certificates, SDS, allergen statement and regulatory declarations

What we can coordinate

  • Supplier specification comparison
  • Document collection and pre-shipment review
  • Packaging and safety-label communication
  • Export-ready quotation support
  • Alternative sulphite or antioxidant-system discussion
  • Customer-specific documentation requests

How to request this product

Send the product name, target grade or reference specification, active content or SO2 equivalent requirement, quantity, destination country, packaging preference, expected shipment date and required documents. If you already purchase Sodium Hydrogen Sulphite, attach or describe your existing specification, label, safety data sheet or certificate of analysis so supplier options can be compared more accurately.

Questions

Useful answers

What is Sodium Hydrogen Sulphite used for in food manufacturing?

Sodium Hydrogen Sulphite is used as a sulphite-based preservative, antioxidant and anti-browning ingredient in selected food and beverage applications where permitted. Its performance depends on pH, matrix, oxygen exposure, processing conditions and residual sulphite limits.

Is Sodium Hydrogen Sulphite the same as Sodium Bisulphite?

Yes. Sodium Hydrogen Sulphite is commonly called Sodium Bisulphite or Sodium Bisulfite. Supplier documents may use different spelling depending on market convention.

Does Sodium Hydrogen Sulphite release sulfur dioxide?

Yes. In moist or acidic environments, Sodium Hydrogen Sulphite can release sulphur dioxide or sulphite species. This is part of its technical function, but it also requires appropriate handling, ventilation, SDS review and label control.

Does this ingredient require sulphite allergen labeling?

Labeling depends on destination-market rules, food category and residual sulphite level. Buyers should verify sulphite declaration thresholds and allergen-label requirements before commercial use.

Can Global Food Additives source Sodium Hydrogen Sulphite?

Global Food Additives can review sourcing options for Sodium Hydrogen Sulphite according to target specification, active content, quantity, destination, packaging, safety requirements and required documentation.

Which documents should be requested?

Buyers commonly request a technical data sheet or specification, certificate of analysis, safety data sheet, origin statement, shelf-life information, label and packing details, impurity statements, assay data, SO2 equivalent and market-specific declarations.

Is this product permitted in every country?

No. Food additive use depends on destination-market rules, food category, maximum permitted sulphite level, residual SO2 requirements, label declaration, allergen statements, technical need and buyer responsibility.

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